High Quality Chinese Factory supply 10294-29-8 Gold(I) chloride
- Molecular Formula: AuCl
- Molecular Weight: 232.419
- Vapor Pressure: 33900mmHg at 25°C
- Melting Point: 289 °C (dec.)(lit.)
- PSA： 0.00000
- Density: 7.57 g/mL at 25 °C(lit.)
- LogP: -2.99850
Gold(I) chloride(Cas 10294-29-8) Usage
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General Description |
Gold(I) chloride, also known as aurous chloride or gold monochloride, is a catalyst used in organic synthesis, particularly in reactions involving the activation of substrates like isocyanides or the cycloisomerization of enynes. It plays a key role in facilitating transformations such as the synthesis of 1-aminoisoquinolines and cis-selective skeletal rearrangements, often in conjunction with other metal catalysts like silver triflate. Additionally, gold(I) chloride forms complexes with phosphinine ligands, exhibiting weak aurophilic or Au···π interactions in crystal structures, which influence their reactivity and structural properties. |
InChI:InChI=1/Au.3ClH/h;3*1H/q+3;;;/p-3
10294-29-8 Relevant articles
Vaporization and vapor complexation in the gold(III) chloride-aluminum(III) chloride system
Nalbandian,Boghosian,Papatheodorou
, p. 1769 - 1773 (1992)
The vapors over solid gold(III) chloride...
Coordination of pyridinethiols in gold(I) complexes
Raeisaenen, Minna T.,Runeberg, Nino,Klinga, Martti,Nieger, Martin,Bolte, Michael,Pyykkoe, Pekka,Leskelae, Markku,Repo, Timo
, p. 9954 - 9960 (2007)
High-yield synthesis of gold(I) thionato...
Synthesis and Structure-Activity Relationship Study of Antimicrobial Auranofin against ESKAPE Pathogens
Wu, Bin,Yang, Xiaojian,Yan, Mingdi
, p. 7751 - 7768 (2019/09/10)
Auranofin, an FDA-approved arthritis dru...
New production of gold resinate
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Paragraph 0017, (2017/03/23)
PROBLEM TO BE SOLVED: conventional gold ...
NON-CYANIDE GOLD COMPOUND
-
Paragraph 0017, (2017/02/28)
PROBLEM TO BE SOLVED: To provide a non-c...
MANUFACTURING METHOD OF GOLD COMPOUND
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Paragraph 0019, (2017/02/28)
PROBLEM TO BE SOLVED: To provide a gold ...
10294-29-8 Process route
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7782-50-5
chlorine
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7440-57-5,457905-15-6
gold
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13453-07-1
gold(III) chloride
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10294-29-8,11118-27-7
gold(I) chloride
| Conditions | Yield |
|---|---|
|
In
neat (no solvent);
powdery Au; at 180 to 190°C;; AuCl and small amounts of AuCl3 obtained;;
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In
neat (no solvent);
powdery Au; at 180 to 190°C;; AuCl and small amounts of AuCl3 obtained;;
|
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-
13453-07-1
gold(III) chloride
-
-
7782-50-5
chlorine
-
-
10294-29-8,11118-27-7
gold(I) chloride
| Conditions | Yield |
|---|---|
|
In
neat (no solvent);
dissociation on heating; equilibrium between373 and 480K;;
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below 100°C very slow reaction;
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In
neat (no solvent);
dissociation on heating; equilibrium between373 and 480K;;
|
|
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below 100°C very slow reaction;
|
10294-29-8 Upstream products
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7440-57-5
gold
-
13453-07-1
gold(III) chloride
-
7782-50-5
chlorine
-
21792-06-3
arsenite
10294-29-8 Downstream products
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10294-31-2
gold(I) iodide
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83846-07-5
N3 P3 (OC6 H4 (C6 H5 )2PAuCl)6
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1420831-83-9
[Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(AuCl)(COD)]
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1446342-19-3
C57 H78 AuClN6 Ni2 O2 PS2 (1+) *ClO4 (1-)
