Chinese Manufacturer supply DIPHENYLGERMANIUM DICHLORIDE 1613-66-7 in stock with high standard
- Molecular Formula: C12H10 Cl2 Ge
- Molecular Weight: 297.707
- Appearance/Colour: clear colorless liquid
- Vapor Pressure: 0.000808mmHg at 25°C
- Melting Point: 9°C
- Refractive Index: n20/D 1.5975(lit.)
-
Boiling Point:
100 °C0.005 mm Hg(lit.)
- Flash Point: 138.9°C
- PSA： 0.00000
- Density: g/cm3
- LogP: 3.97180
DIPHENYLGERMANIUM DICHLORIDE(Cas 1613-66-7) Usage
InChI:InChI=1/C12H10Cl2Ge/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
1613-66-7 Relevant articles
Oligogermanes containing only electron-withdrawing substituents: Synthesis and properties
Zaitsev, Kirill V.,Lam, Kevin,Zhanabil, Zhaisan,Suleimen, Yerlan,Kharcheva, Anastasia V.,Tafeenko, Viktor A.,Oprunenko, Yuri F.,Poleshchuk, Oleg Kh,Lermontova, Elmira Kh,Churakov, Andrei V.
, p. 298 - 309 (2017/04/01)
A series of germanes Ar3GeX, containing ...
A computational study of the fluctional behaviour of group 14 substituted ortho -semiquinone radicals
Ingold,Dilabio, Gino A.
, p. 235 - 240 (2011/04/23)
The dynamics of the 1,4-migration of som...
Reactions of organochlorosilanes with chloro-and organogermanes in the presence of aluminum chloride
Zhun,Sbitneva,Polivanov,Chernyshev
, p. 1564 - 1570 (2008/02/09)
The effect of substituents at the silico...
Reaction of germanium tetrachloride with chloro(phenyl)silanes in the presence of aluminum chloride
Zhun',Sbitneva,Chernyshev
, p. 867 - 869 (2007/10/03)
The effect of the quantity of aluminum c...
1613-66-7 Process route
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91123-26-1
(C6 H5 )3GeGeCl2 C6 H5
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513-81-5
2,3-dimethyl-buta-1,3-diene
-
-
2816-43-5
triphenylgermane
-
-
1626-24-0
chlorotriphenylgermane
-
-
1074-29-9
trichlorophenylgermane
-
-
26311-81-9
1-Chlor-3,4-dimethyl-1-phenyl-1-germano-cyclopent-3-en
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-
1613-66-7
dichlorodiphenylgermane
| Conditions | Yield |
|---|---|
|
In
neat (no solvent);
Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
|
7%
25% 2% 6% 3% |
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3383-21-9
3,5-di-tert-butyl-o-benzoquinone
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-
7366-23-6
diphenylchlorogermane
-
-
1020-31-1,122983-47-5,881376-69-8
3,5-Di-tert-butylcatechol
-
-
110577-23-6
2,2-diphenyl(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolane
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-
1613-66-7
dichlorodiphenylgermane
| Conditions | Yield |
|---|---|
|
In
benzene;
byproducts: HCl; in refluxing benzene, HCl removed by distn. off,; anal., 41% starting germane, 37% quinone left;
|
46%
4% 11% |
|
In
benzene;
byproducts: HCl; 12 h at 60 ° C, mixt. concd. (reduced pressure); anal., 14% starting germane;
|
40%
32% 36% |
1613-66-7 Upstream products
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76-86-8
Triphenylsilyl chloride
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80-10-4
diphenylsilyl dichloride
-
1631-82-9
chloro(methyl)phenylsilane
-
776-76-1
methyldiphenylsilane
1613-66-7 Downstream products
-
1675-58-7
diphenylgermane
-
2816-43-5
triphenylgermane
-
68816-03-5
diphenylgermylene
-
81483-61-6
Ph3 GeGePh2 GePh3
