1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE

  • CAS No.: 22767-90-4
  • Purity: 99%
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1.What is the 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE ?

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione (TFDMHD) may be used in the synthesis of series of NNO ketoimines bearing trifluoromethyl substituents, via Schiff base condensation. It may be used in the synthesis of octahedral Werner-type cobalt(II) complexes. It was used in the preparation of D2-TFDMHD, by mixing with D2O.

3,3-dimethyl-butan-2-one
75-97-8

3,3-dimethyl-butan-2-one

ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione
22767-90-4

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione

Conditions
Conditions Yield
With ethanol; sodium ethanolate;
With sodium hydride; In N,N-dimethyl-formamide;
With sodium ethanolate; In ethanol; at 20 ℃; for 16h;
With potassium tert-butylate;
vanadyl bis(pivaloyltrifluoroacetonate)

vanadyl bis(pivaloyltrifluoroacetonate)

oxo difluoro vanadium (IV)

oxo difluoro vanadium (IV)

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione
22767-90-4

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione

Conditions
Conditions Yield
byproducts: 2,2-diflioro-5-(1,1-dimethylethan)furan-3-one; heating at 460°C;

2.What is the CAS number for 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE ?

The CAS number of 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE is 22767-90-4.

More information of 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE 22767-90-4 are:

CAS?Number

22767-90-4

Density

1.145 g/cm3

Boiling Point

177.5 °C at 760 mmHg

Flash Point

54.6 °C

Vapor Pressure

0.806mmHg at 25°C

Refractive Index

n20/D 1.407(lit.)

HS CODE

29147000

PSA

34.14000

LogP

2.12310

Pka

6.78±0.10(Predicted)

3.What are another words for 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE ?

Synonyms?for?1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE 22767-90-4:(Trifluoroacetyl)pivaloylmethane;1,1,1-Trifluoro-3-pivaloylacetone;2,4-Pentanedione,1,1,1-trifluoro-5,5,5-trimethyl-;5,5-Dimethyl-1,1,1-trifluorohexane-2,4-dione;6,6,6-Trifluoro-2,2-dimethyl-3,5-hexanedione;Pivaloyltrifluoroacetone;

4.What is the molecular formula of 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE?

The chemical formula of ?1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE is?C8H11F3O2 which containing 8 Carbon atoms,11 Hydrogen atoms,3 Fluorine atoms and 2 Oxygen atoms,and the molecular weight of??1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE?is 196.169.

5.What is 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE (22767-90-4) used for?

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione (TFDMHD) is a 1,3-diketone that forms Er(3+) complexes, exhibiting thermally activated slow relaxation of magnetization under a zero direct-current (DC) field. It is a clear colorless to yellow liquid and is utilized in various chemical syntheses and applications.

InChI:InChI=1/C8H11F3O2/c1-7(2,3)5(12)4-6(13)8(9,10)11/h4,12H,1-3H3/b5-4-

Relevant articles related to 1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE:

Article

Source

Synthesis and characterization of the titanium complexes bearing two regioisomeric trifluoromethyl-containing enaminoketonato ligands and their behavior in ethylene polymerization

Ye, Wei-Ping,Mu, Hong-Liang,Shi, Xin-Cui,Cheng, Yan-Xiang,Li, Yue-Sheng

scheme or table, p. 9452 - 9465 (2010/03/04)

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