Factory Sells Best Quality 2-Acetylpyridine 1122-62-9 with steady supply
- Molecular Formula: C7H7NO
- Molecular Weight: 121.139
- Appearance/Colour: clear colorless to slightly brown liquid
- Vapor Pressure: 0.481mmHg at 25°C
- Melting Point: 8-10 ºC
- Refractive Index: n20/D 1.521(lit.)
- Boiling Point: 192.8 ºC at 760 mmHg
- PKA: pK1: 2.643(+1) (25°C)
- Flash Point: 73.3 ºC
- PSA: 29.96000
- Density: 1.06 g/cm3
- LogP: 1.28420
2-Acetylpyridine(Cas 1122-62-9) Usage
|
Identification |
▼▲ CAS.No.:? 1122-62-9? FL.No.:? 14.038 FEMA.No.:? 3251 NAS.No.:? 3251 CoE.No.:? 2315 EINECS.No.:? 214-355-6? JECFA.No.:? 1309 |
|
Regulatory Status |
CoE: Used provisionally. Food: 10 ppm FDA: n/a FDA (other): n/a JECFA: ADI: Acceptable. No safety concern at current levels of intake when used as a flavoring agent (2004). |
|
Natural occurrence |
Reported found in wheaten bread, other types of breads, boiled and cooked beef, grilled and roasted beef, lamb (roasted), lamb and mutton liver, beer, several types of brandy, cocoa, black tea, roasted filbert (Corylus avellano), roasted peanut (Arachis hypogea), heated beans, Bantu beer, coriander seed (Coriandrum sativum L.) and other natural sources. |
|
Production |
It is obtained by bromination of ethylpyrazine, followed by oxidization to obtain it. |
|
Preparation |
From ethyl picolinate |
|
Chemical Structure |
2-Acetylpyridine is an aromatic ketone with the molecular structure consists of a pyridine ring with a ketone group attached at the 2-position. |
|
Usage |
Reported uses (ppm): (FEMA, 1994) ▼▲ Food Category? Usual? Max?? Baked goods? 5 5 Breakfast cereals? 3 3 Cheese? 3 3 Gravies? 3 3 Meat products? 3 3 Milk products? 3 3 Other grains? 3 3 Soft candy? 3 3 Soups? 3 3 |
|
Taste threshold values |
Taste characteristics at 10 ppm: cornmeal with nutty, bready nuance |
|
General Description |
2-Acetylpyridine is a volatile flavor compound found in rye bread crust and roasted sesame. It has also been identified as a key contributor to the “scented rice”-like aroma in Yahonkaoluo leaves and Xiangjing-8618 rice. |
InChI:InChI=1/C7H7NO/c1-6(9)7-4-2-3-5-8-7/h2-5H,1H3
1122-62-9 Relevant articles
Highly efficient Au hollow nanosphere catalyzed chemo-selective oxidation of alcohols
Sasidharan, Manickam,Anandhakumar, Sundaramurthy,Bhanja, Piyali,Bhaumik, Asim
, p. 87 - 94 (2016)
Micelles of poly(styrene-b-2-vinyl pyrid...
Kinetic Resolution of 1-Aryl- and 1-Heteroaryl Ethanols by Oxidation with Baker's Yeast
Fantin, Giancarlo,Fogagnolo, Marco,Medici, Alessandro,Pedrini, Paola,Poli, Silvia,Sinigaglia, Milena
, p. 883 - 884 (1993)
The kinetic resolution of racemic 1-aryl...
Highly efficient dehydrogenation of secondary alcohols catalyzed by iridium-CNP complexes
Wang, Dawei,Zhao, Keyan,Yang, Shuyan,Ding, Yuqiang
, p. 2016 - 2020 (2014)
A new highly practical method is present...
-
Walker
, p. 1047,1048 (1960)
-
Aerobic oxidation of alcohols at room temperature and atmospheric conditions catalyzed by reusable gold nanoclusters stabilized by the benzene rings of polystyrene derivatives
Miyamura, Hiroyuki,Matsubara, Ryosuke,Miyazaki, Yoji,Kobayashi, Shu
, p. 4151 - 4154 (2007)
(Chemical Equation Presented) Lock up yo...
Modular O-: Vs. N-coordination of pyridylidene amide ligands to iron determines activity in alcohol oxidation catalysis
Verhoeven, Dide G. A.,Albrecht, Martin
, p. 17674 - 17682 (2020)
A family of polydentate pyridine-substit...
Direct conversion of heteroaromatic esters to methyl ketones with trimethylaluminum: Nonsymmetrically disubstituted 1,2,4,5-tetrazines
Girardot, Marc,Nomak, Rana,Snyder, John K.
, p. 10063 - 10068 (1998)
-
Acylation of Grignard reagents mediated by N-methylpyrrolidone: A remarkable selectivity for the synthesis of ketones
Gowda, Maravanhalli Sidde,Pande, Sushanth Sudhir,Ramakrishna, Ramesha Andagar,Prabhu, Kandikere Ramaiah
, p. 5365 - 5368 (2011)
An efficient user-friendly method of acy...
Studies on pyrazines; 38: Acylation of bromopyrazines and 2-bromopyridine via copper-cocatalytic stille reaction
Sato,Narita
, p. 1551 - 1555 (2001)
Synthesis of acetylpyrazines 3 and propi...
New Organocatalyst scaffolds with high activity in promoting hydrazone and oxime formation at neutral pH
Larsen, Dennis,Pittelkow, Michael,Karmakar, Saswata,Kool, Eric T.
, p. 274 - 277 (2015)
The discovery of two new classes of cata...
Methoxy(2-pyridyl)ketene
Andersen, Heidi Gade,Bednarek, Pawel,Wentrup, Curt
, p. 519 - 524 (2003)
The matrix photolysis of 3-methoxy-carbo...
Gold-platinum bimetallic clusters for aerobic oxidation of alcohols under ambient conditions
Miyamura, Hiroyuki,Matsubara, Ryosuke,Kobayashi, Shu
, p. 2031 - 2033 (2008)
We have developed gold/platinum alloyed ...
4-CH3CONH-TEMPO/Peracetic Acid System for a Shortened Electron-Transfer-Cycle-Controlled Oxidation of Secondary Alcohols
Zhang, Shufang,Miao, Chengxia,Xia, Chungu,Sun, Wei
, p. 1865 - 1870 (2015)
We have developed a 2,2,6,6-tetramethylp...
Efficient aerobic oxidation of alcohols using a hydrotalcitesupported gold nanoparticle catalyst
Mitsudome, Takato,Noujima, Akifumi,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
, p. 1890 - 1896 (2009)
Hydrotalcite-supported gold nanoparticle...
Silver nanoparticles immobilized onto poly(4-vinylpyridine)-functionalized magnetic nanoparticles: A robust magnetically recyclable catalyst for oxidant-free alcohol dehydrogenation
Bayat, Ahmad,Shakourian-Fard, Mehdi,Talebloo, Nazanin,Hashemi, Mohammed Mahmoodi
, (2018)
A heterogeneous and recyclable catalyst ...
Boosting activity of molecular oxygen by pyridinium-based photocatalysts for metal-free alcohol oxidation
Ma, Shuai,Cui, Jing-Wang,Rao, Cai-Hui,Jia, Meng-Ze,Chen, Yun-Rui,Zhang, Jie
, p. 1337 - 1343 (2021)
An eco-friendly and economical approach ...
Selective electrochemical oxidation of aromatic hydrocarbons and preparation of mono/multi-carbonyl compounds
Li, Zhibin,Zhang, Yan,Li, Kuiliang,Zhou, Zhenghong,Zha, Zhenggen,Wang, Zhiyong
, p. 2134 - 2141 (2021/09/29)
A selective electrochemical oxidation wa...
Selective Electrochemical Oxygenation of Alkylarenes to Carbonyls
Li, Xue,Bai, Fang,Liu, Chaogan,Ma, Xiaowei,Gu, Chengzhi,Dai, Bin
supporting information, p. 7445 - 7449 (2021/10/02)
An efficient electrochemical method for ...
Visible-light photocatalytic selective oxidation of C(sp3)-H bonds by anion-cation dual-metal-site nanoscale localized carbon nitride
Duan, Limei,Li, Peihe,Li, Wanfei,Liu, Jinghai,Liu, Ying,Liu, Zhifei,Lu, Ye,Sarina, Sarina,Wang, Jinghui,Wang, Yin,Wang, Yingying,Zhu, Huaiyong
, p. 4429 - 4438 (2021/07/12)
Selective oxidation of C(sp3)-H bonds to...
Dimensional Reduction of Eu-Based Metal-Organic Framework as Catalysts for Oxidation Catalysis of C(sp3)–H Bond
Yan, Jun,Yu, Wei-Dong,Zhang, Yin,Zhao, Cai-Feng
, (2021/12/27)
Developing new catalysts for highly sele...
1122-62-9 Process route
-
-
87251-88-5
Fructose-methionine Amadori intermediate
-
-
64265-26-5
2,4-Dimethyltetrahydrofuran
-
-
96-54-8
N-Methylpyrrole
-
-
109-08-0
2-Methylpyrazine
-
-
1122-62-9
2-acetylpyridine
-
-
3268-49-3
3-(methylsulfenyl)propanal
-
-
3740-59-8
3,4-dihydro-6-methyl-2H-pyran-2-one
| Conditions | Yield |
|---|---|
|
at 260 ℃;
for 0.0833333h;
Thermal degradation;
|
70%
|
-
-
1122-62-9
2-acetylpyridine
-
-
463-79-6
carbonic-acid
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride;
|
1122-62-9 Upstream products
-
100-69-6
2-vinylpyridine
-
100-70-9
2-Cyanopyridine
-
917-64-6
methyl magnesium iodide
-
2524-52-9
ethyl-2-picolinate
1122-62-9 Downstream products
-
26482-00-8
1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide
-
67674-34-4
2-[2]pyridyl-butan-2-ol
-
57882-27-6
2-(pyridin-2-yl)-quinoline-4-carboxylic acid
-
16232-04-5
(E)-3-(3-nitrophenyl)-1-(pyridin-2-yl)prop-2-en-1-one